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The duration of adjustment depends on the strength of the negative feedback to the initial shock. Where a shock initially induces positive feedback such as thermal runaway , the new equilibrium can be far from the old one, and can take a long time to reach. In some dynamic systems , the end-state cannot be determined from the shock. The principle is typically used to describe closed negative-feedback systems, but applies, in general, to thermodynamically closed and isolated systems in nature, since the second law of thermodynamics ensures that the disequilibrium caused by an instantaneous shock must have a finite half-life. While well rooted in chemical equilibrium and extended into economic theory, Le Chatelier's principle can also be used in describing mechanical systems in that a system put under stress will respond in such a way as to reduce or minimize that stress. Moreover, the response will generally be via the mechanism that most easily relieves that stress. Shear pins and other such sacrificial devices are design elements that protect systems against stress applied in undesired manners to relieve it so as to prevent more extensive damage to the entire system, a practical engineering application of Le Chatelier's principle. Chemistry[ edit ] Effect of change in concentration[ edit ] Changing the concentration of a chemical will shift the equilibrium to the side that would counter that change in concentration.

Define le chateliers principle Video

GCSE Chemistry - Le Chatelier's Principle #42 (Higher Tier) define le chateliers principle. Define le chateliers principle

Effect of Temperature Change on Le Chatelier’s Principle

Effect of concentration change Change in concentration is directly affected by equilibrium. If the concentration of the reactant increase, the equilibrium is disturbed. If the concentration of the product increases, the equilibrium is disturbed.

define le chateliers principle

The endothermic reactionin which heat is absorbed and is favored at high temperature. And with the rise in temperature, the equilibrium will shift towards the backward direction and the concentration of the product is decreased. For Endothermic Reaction According to the principle, if the temperature is decreased in an endothermic reaction the equilibrium definne from backward direction and a result of this concentration of products is decreasing.

Expert Answer

And with the rise in temperature, the equilibrium will shift from the forward direction and the concentration of the product is increased. Effect of Pressure Change Change in pressure only affects gaseous equilibrium because the change in pressure is related to the change in volume. Pressure has no effect on solids and liquids because they are almost incompressible, hence their volumes are very little affected by the change in pressure.

Effect of Catalyst A catalyst has no effect on the equilibrium.

define le chateliers principle

It increases the rate of reaction by lowering the energy of activation and enables equilibrium to be reached more quickly.]

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